82352-39-4

Basic information

• Product Name: Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-
• CAS NO: 82352-39-4
• Molecular Formula: C12H14O2S
• Molecular Weight: 222.308
• Mol File: 82352-39-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-(82352-39-4)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-(82352-39-4)

Safety Data

• Hazardous Substances Data: 82352-39-4(Hazardous Substances Data)

Upstream product

• 106-45-6 para-thiocresol 
• 933-00-6 p-methylbenzenesulfenyl chloride 
• 83074-78-6 (3-Methyl-1,2-butadienyl)(p-tolyl)sulfoxid 
• 98-59-9 p-toluenesulfonyl chloride 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 109787-25-9 1,1-dimethyl-2-propynyl 4-methylbenzenesulfinate 

Downstream Products

• 791064-99-8 (1Z)-3-methyl-1-(4-methylphenylsulfonyl)buta-1,3-diene 
• 91873-76-6 1-<<3-methyl-2-<(3-methyl-2-butenyl)oxy>-2-butenyl>sulfonyl>-4-methylbenzene 
• 109787-56-6 (E)-3,3-dimethyl-1-<(4-methylphenyl)sulfonyl>-5-hepten-2-one 

Relevant articles and documents

Rhodium-Catalyzed Highly Regio- and Enantioselective Hydrogenation of Tetrasubstituted Allenyl Sulfones: An Efficient Access to Chiral Allylic Sulfones

A highly regio- and enantioselective hydrogenation of challenging tetrasubstituted allenyl sulfones has been developed, affording chiral allylic sulfones in good yields with excellent regio- and enantioselectivities (up to 99 % yield and 99 % ee). This me

Preparation of Propargylic Sulfinates and their [2,3]-Sigmatropic Rearrangement to Allenic Sulfones

The scope of the [2,3]-sigmatropic rearrangement of propargylic sulfinates to allenic sulfones by silver catalysis was expanded. A series of new propargylic sulfinate esters was generated from a variety of aromatic and heteroaromatic sulfonyl chlorides an

Silver-catalyzed rearrangement of propargylic sulfinates to allenic sulfones

Treatment of propargylic sulfinate esters with 2 mol% of silver hexafluoroantimonate results in the rapid formation of allenic sulfones in essentially quantitative yield.