82360-68-7Relevant academic research and scientific papers
Selective transition-metal-free vicinal cis-dihydroxylation of saturated hydrocarbons
Bering, Luis,Antonchick, Andrey P.
, p. 452 - 457 (2016/12/30)
A transition-metal-free cis-dihydroxylation of saturated hydrocarbons under ambient reaction conditions has been developed. The described approach allows a direct and selective synthesis of vicinal diols. The new reaction thereby proceeds via radical iodination and a sequence of oxidation steps. A broad scope of one-pot dual C(sp3)-H bond functionalization for the selective synthesis of vicinal syn-diols was demonstrated.
Selective alkene oxidation with H2O2 and a heterogenized Mn catalyst: Epoxidation and a new entry to vicinal cis-diols
De Vos, Dirk E.,De Wildeman, Stefaan,Sels, Bert F.,Grobet, Piet J.,Jacobs, Pierre A.
, p. 980 - 983 (2007/10/03)
Covalent anchoring of 1,4-dimethyl-1,4,7-triazacyclononane on silica gel is the first step in the preparation of a heterogenized Mn catalyst. When H2O2 is used as the oxidant, this material can catalyze the vicinal cis- dihydroxylation of disubstituted olefins, as shown schematically here. Both enantiomers of the product are obtained.
PHOTOCHEMICAL REACTION OF ALCOHOLS-I IRRADIATION OF ALIPHATIC ALCOHOLS
Balsells, R. Erra,Frasca, A. R.
, p. 245 - 255 (2007/10/02)
The UV irradiation of aliphatic alcohols gave α-glycols as the principal products.The values of the dl-α-glycol to meso-α-glycol ratios obtained in each example were analyzed.The stereochemical course of the formation of α-glycols, their conformations and configurations were established on basis of 1H NMR data.
