82415-90-5Relevant academic research and scientific papers
Preparation of Bifunctional Allylboron Reagent and Application to Aldehyde Allylboration
Liu, Jiaming,Gao, Shang,Chen, Ming
, p. 1659 - 1662 (2019)
Synthesis of a bifunctional allylboron reagent via Ni-catalyzed borylation of allylic acetate is reported. Subsequent allylation of aldehydes gave homoallylic alcohols in good yields. The allylsilane moiety in the alcohol product serves as a useful handle
Synthesis of functionalized allylsilanes using 3-(stannyl)-2-(silylmethyl)propene
Kang, Kyung-Tae,Sung, Tae Myung,Kim, Jun Keun,Kwon, Yong Mok
, p. 1173 - 1181 (1997)
Reactions of 3-tributylstannyl-2-(trimethylsilylmethyl)propene with acid chlorides or aldehydes proceed smoothly without any catalytic activation to afford allylsilanes bearing various functionalities.
Synthesis of highly substituted 2,6-anti-configured tetrahydropyrans. First steps towards an efficient access to amphidinol 3 ring system
Dubost, Christophe,Markó, Istvan E.,Bryans, Justin
, p. 4005 - 4009 (2007/10/03)
Highly functionalised and polysubstituted tetrahydropyrans, akin to the middle core of the amphidinols, can be efficiently synthesised, with full stereocontrol and in good yields, using as key steps an anti-allylation reaction coupled with an intramolecul
Preparation and synthetic utility of 2-methylselenomethyl allyl methyl selenide. A valuable precursor to 2-silylmethylallyllithiums
Krief, Alain,Dumont, Willy,Markó, István E.,Murphy, Fiona,Vanherck, Jean-Christophe,Duval, Romain,Ollevier, Thierry,Abel, Ulrich
, p. 1219 - 1222 (2007/10/03)
3-Lithio-2-[silylmethyl]propenes, easily prepared from 3-methylseleno-2-[silylmethyl]propenes by the cleavage of the C-Se bond, are useful intermediates for the preparation of a variety of functionalised allylsilanes. These allylsilanes are interesting bu
Selective Electrophilic Addition of Mixed Bifunctionalized Trimethylenemethane Dianion Synthons
Majetich, George,Nishidie, Hisaya,Zhang, Yong
, p. 453 - 458 (2007/10/02)
Three trimethylenemethane dianion synthons showed a profound divergence of reactivity, based upon the choice catalyst employed.
PREPARATION AND SYNTHETIC APPLICATION OF 2-BROMOALLYLTRIMETHYLSILANE AS A 1-HYDROXYMETHYLVINYL ANION EQUIVALENT
Nishiyama, Hisao,Yokoyama, Hiroshi,Narimatsu, Shinzo,Itoh, Kenji
, p. 1267 - 1270 (2007/10/02)
The 1-trimethylsilylmethylvinyl group, as a 1-hydroxymethylvinyl equivalent, was readily introduced to epoxides with the corresponding Grignard reagent derived from 2-bromoallyltrimethylsilane.Obtained 2-(2-hydroxyethyl)-allylsilanes were converted to α-methylene-γ-lactones via diols.
