824427-16-9 Usage
Explanation
The compound is composed of 12 carbon atoms, 14 hydrogen atoms, and 3 oxygen atoms.
Explanation
It is a derivative of naphthoquinone, a naturally occurring compound found in certain plants and also produced synthetically.
Explanation
The compound has a cyclic structure with additional methyl and methoxy groups attached to it.
Explanation
It is an organic compound, which means it primarily consists of carbon and hydrogen atoms.
Explanation
It is commonly used in the production of dyes, serves as a precursor for pharmaceuticals, and acts as an intermediate in organic synthesis.
Explanation
The compound has potential applications in the field of medicinal chemistry and can be used as a building block for the synthesis of other complex molecules.
Explanation
It is important to handle 1,4-Naphthoquinone,4a,5,8,8a-tetrahydro-8-methoxy-2,4a-dimethyl-(5CI) with care, as it may have toxic or irritant properties that could pose health risks.
Derivative of
Naphthoquinone
Structure
Tetrahydro-8-methoxy-2,4a-dimethyl
Type
Organic compound
Applications
Dyes, pharmaceuticals, and organic synthesis
Potential Applications
Medicinal chemistry and complex molecule synthesis
Safety Precautions
Toxic or irritant properties
Check Digit Verification of cas no
The CAS Registry Mumber 824427-16-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,2,4,4,2 and 7 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 824427-16:
(8*8)+(7*2)+(6*4)+(5*4)+(4*2)+(3*7)+(2*1)+(1*6)=159
159 % 10 = 9
So 824427-16-9 is a valid CAS Registry Number.
824427-16-9Relevant academic research and scientific papers
Morimoto, Kyosuke,Le, Thien Phuc,Manna, Sudipta Kumar,Kiran, I. N. Chaithanya,Tanaka, Shinji,Kitamura, Masato
, p. 3283 - 3290 (2019)
A ZnII complex of a C2-chiral bisamidine-type sp2N bidentate ligand (LR) possessing two dioxolane rings at both ends catalyzes a highly efficient quinone asymmetric Diels-Alder reaction (qADA) between o-alkoxy-p-benzoquinones and 1-alkoxy-1,3-butadienes to construct highly functionalized chiral cis-decalins, proceeding in up to a >99:1 enantiomer ratio with a high generality in the presence of H2O (H2O:ZnII=4–6:1). In the absence of water, little reaction occurs. The loading amount of the chiral ligand can be minimized to 0.02 mol % with a higher Zn/LR ratio. This first success is ascribed to a supramolecular 3D arrangement of substrates, in which two protons of an “H2O-ZnII” reactive species make a linear hydrogen bond network with a dioxolane oxygen atom and one-point-binding diene; the ZnII atom captures the electron-accepting two-points-binding quinone fixed on the other dioxolane oxygen atom via an n-π* attractive interaction. The mechanisms has been supported by 1H NMR study, kinetics, X-ray crystallographic analyses of the related ZnLR complexes, and ligand and substrate structure-reactivity-selectivity relationship.
