82448-96-2

Basic information

• Product Name: (3-chloropropionyl)diphenylphosphane
• Synonyms: (3-chloropropionyl)diphenylphosphane
• CAS NO: 82448-96-2
• Molecular Weight: 276.702
• Mol File: 82448-96-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3-chloropropionyl)diphenylphosphane(CAS DataBase Reference)
• NIST Chemistry Reference: (3-chloropropionyl)diphenylphosphane(82448-96-2)
• EPA Substance Registry System: (3-chloropropionyl)diphenylphosphane(82448-96-2)

Safety Data

• Hazardous Substances Data: 82448-96-2(Hazardous Substances Data)

Upstream product

• 625-36-5 2-chloropropionyl chloride 
• 17154-34-6 (trimethylsilyl)diphenylphosphine 

Downstream Products

• 83352-18-5 cis-bromotetracarbonyl[(3-chloropropionyl)diphenylphosphane]manganese 

Relevant articles and documents

Synthesis, Thermal Behaviour, and Stabilization of (3-Chloroacyl)- and (4-Chloroacyl)diphenylphosphanes

The propionyl- and butyryldiphenylphosphanes RC(O)-PPh2 (2a - c) 2 (c) are obtained by reaction of the acyl chlorides 1a - c with (CH3)3Si-PPh2 at -40 deg C in ether. 2a, b are thermally labile and polymerize under elimination of HCl.The formation of ketenes is not observed.By the reaction with BrMn(CO)5 2a, b were stabilized as complexes (OC)4BrMnPPh2C(O)R (3a, b) and compared with 3d, e .On the basis of an X-ray crystallographic investigation 3b crystallizes monoclinicly in the space group P21/c with Z = 4.