82452-68-4Relevant academic research and scientific papers
Addition-1,4 d'enethiolates lithies de dithioesters aux cetones ethyleniques
Berrada, Said,Metzner, Patrick,Rakotonirina, Rose
, p. 881 - 890 (2007/10/02)
Deprotonation of carboxylic dithioesters with LDA gives rise to thermally stable lithium thioenolates that have been submitted to the action of various enones under kinetic conditions.Selective carbon-1,4-addition has been observed.Lithium thioenolates ma
Kinetic 1,4-Addition of a Dithioacetate Enolate to α-Enones
Metzner, Patrick
, p. 335 - 336 (2007/10/02)
Lithium methyl dithioacetate reacts with enones at low temperature via a selective 1,4-C-addition to give 5-oxodithioesters; further elaboration by thiophilic addition and alkylation furnishes masked 1,5-dicarbonyl compounds.
