82456-65-3Relevant academic research and scientific papers
STUDIES ON THE INTERACTION OF ISOCYANIDES WITH TRANSITION METAL COMPLEXES. XXVII. PREPARATION OF ZEROVALENT ISOCYANIDE COMPLEXES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN. THE CRYSTAL STRUCTURE OF HEXAKIS(2,6-XYLYLISOCYANIDE)MOLYBDENUM CONTAINING BENZENE AS A SOLVATED MOLECULE
Yamamoto, Yasuhiro,Yamazaki, Hiroshi
, p. 191 - 200 (2007/10/02)
Hexakis(isocyanide)metals, M(RNC)6 (M=Cr, Mo, W; R=2,6-Me2C6H4, 2,4,6-Me3C6H2, 2,4-t-Bu2-6-MeC6H2, 2,4,6,-t-Bu3C6H2 and t-Bu), were prepared by the reduction of a halide of chromium(III), molybdenum(IV), molybdenum(V) or tungsten(VI) with sodium amalgam in the presence of an isocyanide.An X-ray crystallographic study of Mo(2,6-Me2C2H3NC)6*C6H6 revealed that the molybdenum atom is approximately octahedrally coordinated by six isocyanide ligands.
Metal Carbonyl Substitution Reactions catalysed by Transition Metal Complexes
Albers, Michel O.,Coville, Neil J.,Ashworth, Terence V.,Singleton, Eric,Swanepoel, Hester E.
, p. 489 - 490 (2007/10/02)
The reaction of Fe(CO)5 with isonitriles RNC in the presence of CoCl2*2H2O as catalyst to give Fe(CO)5-n(RNC)n (n = 1-5) is reported.
