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Asymmetric allylic alkylation with palladium coordinated to a new optically active pyrazolylmethane ligand
Bovens, M.,Togni, A.,Venanzi, L. M.
, p. C28 - C31 (1993)
The optically active pyrazole 4R-methyl-7R-isopropyl-4,5,6,7-tetrahydroindazole, 3, was prepared from (-)-menthone 1, and used for the preparation of the ligands bis(4R-methyl-7R-isopropyl-4,5,6,7-tetrahydro-N2-indazolyl)methane, 5, bis(4R-meth
