82469-72-5Relevant articles and documents
Radical-mediated bromination of carbohydrate derivatives: Searching for alternative reaction conditions without carbon tetrachloride
Czifrák, Katalin,Somsák, László
, p. 8849 - 8852 (2002)
KBrO3-Na2S2O4 in CH2Cl2-H2O or PhCF3-H2O biphasic solvent systems was applied to the bromination of several monosaccharide derivatives having capto-datively
Sugar Enolones, XVIII. - Stereocontrolled Functionalization at Proanomeric Centres by Photobromination. - A Novel Efficient Access to Oxo- and Oximinoglycosyl Bromides
Lichtenthaler, Frieder W.,Jarglis, Pan,Hempe, Walter
, p. 1959 - 1972 (2007/10/02)
Suitably O-blocked monosaccharides carrying an electron acceptor group such as an oxo or oximino function next to a proanomeric centre, readily homolyze the corresponding push-pull-substituted C-H bond to give under photobromination conditions the respect