82480-88-4Relevant academic research and scientific papers
PHOTOREDUCTION DE LA BENZOPHENONE PAR DES PHTALIMIDINES ET DES DIHYDRO ISOQUINOLONES. ETUDE CHIMIQUE ET PAR RMN PNIC
Gramain, J. C.,Simonet, N.,Vermeersch, G.,Febvay-Garot, N.,Caplain, S.,Lablache-Combier, A.
, p. 539 - 550 (2007/10/02)
Benzophenone is photoreduced by phtalimidines and dihydro isoquinolones.The hydrogen atom α to the nitrogen atom is abstracted and radical coupling leads to adducts.CIDNP studies of these adducts show inversion of polarisation for the adduct on the N-alkyl chain when the nitrogen is bound to a benzylic methylene.This inversion is explained by considering that the radical on the N-alkyl chain derives from the radical on the ring.
