825-94-5

Basic information

• Product Name: CHLOROPHENYLTRICHLOROSILANE
• Synonyms: Silane, trichloro(4-chlorophenyl)-;CHLOROPHENYLTRICHLOROSILANE, MIXED M,P-ISOMERS;P-CHLOROPHENYLTRICHLOROSILANE;TRICHLORO(4-CHLOROPHENYL)SILANE;trichloro(chlorophenyl)silane;trichloro(p-chlorophenyl)silane;TRICHLORO(4-CHLOROPHENHYL)SILANE, 97%;Chlorophenyltrichlorosilanemixedisomers
• CAS NO: 825-94-5
• Molecular Formula: C₆H₄Cl₄Si
• Molecular Weight: 245.99
• EINECS: 212-551-6
• Product Categories: Protecting and Derivatizing Reagents;Protection and Derivatization;Silicon-Based
• Mol File: 825-94-5.mol

Chemical Properties

• Melting Point: <0°C
• Boiling Point: 105 °C15 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.424 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.147mmHg at 25°C
• Refractive Index: n20/D 1.544(lit.)
• CAS DataBase Reference: CHLOROPHENYLTRICHLOROSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: CHLOROPHENYLTRICHLOROSILANE(825-94-5)
• EPA Substance Registry System: CHLOROPHENYLTRICHLOROSILANE(825-94-5)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 2987 8/PG 2
• WGK Germany: 3
• TSCA: Yes
• HazardClass: 8
• PackingGroup: II
• Hazardous Substances Data: 825-94-5(Hazardous Substances Data)

Usage

Uses

Used in Polymer Synthesis:
Chlorophenyltrichlorosilane is used as a coupling agent for enhancing the properties of polymers. Its ability to react with various functional groups allows for the formation of siloxane polymers, which are integral to the development of high-performance materials.
Used in Advanced Material Production:
In the industry of advanced materials, chlorophenyltrichlorosilane serves as a surface modifier. Its application results in improved material characteristics, such as enhanced durability and stability, which are crucial for specialized applications.
Used in Pharmaceutical Manufacturing:
Chlorophenyltrichlorosilane is utilized as an intermediate in the production of pharmaceuticals. Its role in the synthesis of various medicinal compounds underscores its importance in the development of new drugs and therapies.
Used in Agrochemical Production:
Similarly, in the agrochemical sector, chlorophenyltrichlorosilane is employed as an intermediate. It contributes to the formulation of effective crop protection agents and other agricultural products, thereby supporting agricultural productivity and sustainability.
Used in Organic Compound Synthesis:
Chlorophenyltrichlorosilane is also used in the synthesis of other organic compounds. Its reactivity makes it a valuable component in the creation of a wide range of organic chemicals used across various industries.

InChI:InChI=1/C6H4Cl4Si/c7-5-1-3-6(4-2-5)11(8,9)10/h1-4H

Upstream product

• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 98-13-5 Phenyltrichlorosilane 
• 51833-36-4 4-chlorophenylmagnesium chloride 
• 106-39-8 bromochlorobenzene 
• 10026-04-7 tetrachlorosilane 

Downstream Products

• 10557-71-8 4-chlorophenyltrimethylsilane 
• 18037-03-1 (4-chlorophenyl)triethylsilane 
• 17943-23-6 (4-chloro-phenyl)-tripropyl-silane 
• 29025-67-0 1-(4-chlorophenyl)silatrane 
• 1242769-19-2 Tsi(p-ClC₆H₄)SiCl₂ 
• 17478-32-9 α-[dichloro-(4-chloro-phenyl)-silanyloxy]-isobutyronitrile 

Relevant articles and documents

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Reaction of the Grignard reagent, p-ClC6H4MgCl, with SiCl4 in toluene gave (p-ClC6H4) 2SiCl2, which was treated with KHF2 to give (p-ClC6H4)2SiF2 (1). Reaction of the latter with [(Me3Si)3C]Li in THF leads to the preparation of [(Me3Si)3C](p-ClC6H4) 2SiF (2). Treatment of (2) with LiAlH4 gave [(Me 3Si)3C](p-ClC6H4)2SiH (3) and [(Me3Si)3C](p-ClC6H4)(C 6H5)SiH (4). [(Me3Si)3C](p-ClC 6H4)SiCl2 (5) was also prepared from the reaction of (p-ClC6H4)SiCl3 with [(Me 3Si)3C]Li in a similar manner. The new highly sterically hindered organosilicon reagents (2) to (5) have been fully characterized by IR, 1H and 13C NMR, and mass spectrometry as well as elemental analysis. Copyright Taylor & Francis Group, LLC.