82509-41-9

Basic information

• Product Name: (1S,4aS,6S,7S,7aS)-1-(beta-D-glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid
• CAS NO: 82509-41-9
• Molecular Formula: C₁₆H₂₄O₁₀
• Molecular Weight: 376.3558
• Mol File: 82509-41-9.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 646.3°C at 760 mmHg
• Flash Point: 235.6°C
• Density: 1.6g/cm³
• Vapor Pressure: 1.97E-19mmHg at 25°C
• Refractive Index: 1.633
• CAS DataBase Reference: (1S,4aS,6S,7S,7aS)-1-(beta-D-glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4aS,6S,7S,7aS)-1-(beta-D-glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid(82509-41-9)
• EPA Substance Registry System: (1S,4aS,6S,7S,7aS)-1-(beta-D-glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid(82509-41-9)

Safety Data

• Hazardous Substances Data: 82509-41-9(Hazardous Substances Data)

Usage

General Description

The chemical "(1S,4aS,6S,7S,7aS)-1-(beta-D-glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid" is a complex compound with a hexahydrocyclopenta[c]pyran structure, which contains a beta-D-glucopyranosyloxy group and a carboxylic acid functional group. It also has a hydroxyl and a methyl group attached to the cyclopenta[c]pyran ring. (1S,4aS,6S,7S,7aS)-1-(beta-D-glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid is a naturally occurring molecule and is often found as a component of certain plants or microorganisms. It may have potential pharmaceutical or biological activities, and its complex structure makes it a subject of interest for further research and exploration.

Upstream product

• 67-56-1 methanol 
• 1167573-25-2 2'-O-p-hydroxybenzoylloganic acid 
• 79636-19-4 (E)-3-Phenyl-acrylic acid (1S,4aS,6S,7R,7aS)-4-formyl-7-methyl-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-6-yl ester 
• 79637-89-1 5-hydroxycampenoside 
• 22487-36-1 bis-desoxy-dihydro-monotropein 
• 79636-20-7 (1S,4aS,6S,7R,7aS)-7-Methyl-6-[(E)-(3-phenyl-acryloyl)oxy]-1-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,6,7,7a-hexahydro-cyclopenta[c]pyran-4-carboxylic acid 
• 18524-94-2 loganin 
• 139501-37-4 Ligustrinoside 

Downstream Products

• 18524-94-2 loganin 
• 132237-63-9 alyxialactone 
• 132339-37-8 4-epi-Alyxialactone 
• 20586-11-2 2',3',4',6',7-penta-O-acetylloganin 

Relevant articles and documents

Algidisides I and II, New Iridoid Glycosides from Gentiana algida

Two new iridoid glycosides, algidiside I [2′-(2′′,3′′-dihydroxybenzoyl)loganic acid] (1) and algidiside II [6′-(2′′,3′′-dihydroxybenzoyl)loganic acid] (2), and 14 known iridoids including for the first time from the aerial part of Gentiana algida Pall. 2′

7-Deoxyloganin 7-hydroxylase in Lonicera japonica cell cultures

The activity of 7-deoxyloganin 7-hydroxylase, an enzyme catalyzing the conversion of 7-deoxyloganin into loganin, was detected in a microsomal preparation from the cell suspension cultures of Lonicera japonica. It was dependent on NADPH and molecular oxyg

Iridoid glucosides from Picconia excelsa

An investigation of the iridoids of Picconia excelsa from Tenerife provided 17 iridoid glucosides together with verbascoside. Major constituents (> 0.5%) were loganin, ketologanin, oleoacteoside and the new picconioside I- a bisiridoid consisting of loganin esterified with deoxyloganin. Minor constituents were secoxyloganin, 8-epi-kingiside, oleoside 11-methyl ester, excelsioside, ligstroside and loganic acid together with the new compounds ketologanic acid, 6β-hydroxy-7-epi-loganin and picconiosides II-V, the latter four being esters of loganin and menthiafolic, foliamenthic, 6-(Z)- foliamenthic or 6,7-dihydrofoliamenthic acid. The structures were mainly elucidated by NMR spectroscopy.