82522-19-8

Basic information

• Product Name: [Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]⁽¹⁺⁾*Cl^(1-)=[Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]Cl
• CAS NO: 82522-19-8
• Molecular Weight: 999.339
• Mol File: 82522-19-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]⁽¹⁺⁾*Cl^(1-)=[Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]⁽¹⁺⁾*Cl^(1-)=[Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]Cl(82522-19-8)
• EPA Substance Registry System: [Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]⁽¹⁺⁾*Cl^(1-)=[Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]Cl(82522-19-8)

Safety Data

• Hazardous Substances Data: 82522-19-8(Hazardous Substances Data)

Upstream product

• 67-66-3 chloroform 
• 15043-47-7 [Rh(bis(diphenyl)phosphinoethane)₂][Cl] 
• 10544-50-0 cyclo-octasulfur 

Downstream Products

• 15043-47-7 [Rh(bis(diphenyl)phosphinoethane)₂][Cl] 

Relevant articles and documents

Synthesis of thiiranes by rhodium-catalyzed sulfur addition reaction to reactive alkenes

A rhodium complex derived from RhH(PPh3)4, dppe, and 4-ethynyltoluene catalyzes the addition reaction of sulfur to norbornenes giving the corresponding thiiranes under acetone reflux conditions. The rhodium complex effectively transfers a sulfur atom to the double bond from sulfur, and exo-adducts are obtained. The reaction is also applicable to (E)-cyclooctene and cyclic allenes. The ring-opening reaction of the thiiranes with lithium aluminium hydride gives the corresponding thiols. This journal is