82537-34-6

Basic information

• Product Name: (E)-1-Phenyl-dodec-1-en-4-ol
• Synonyms: (E)-1-Phenyl-dodec-1-en-4-ol
• CAS NO: 82537-34-6
• Molecular Weight: 260.42
• Mol File: 82537-34-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1-Phenyl-dodec-1-en-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-Phenyl-dodec-1-en-4-ol(82537-34-6)
• EPA Substance Registry System: (E)-1-Phenyl-dodec-1-en-4-ol(82537-34-6)

Safety Data

• Hazardous Substances Data: 82537-34-6(Hazardous Substances Data)

Upstream product

• 2404-44-6 1,2-Epoxydecane 
• 100-52-7 benzaldehyde 
• 19493-09-5 Methylenetriphenylphosphorane 
• 124-19-6 nonan-1-al 
• 4392-24-9 Cinnamyl bromide 
• 16215-11-5 trans-cinnamyl p-tolyl sulfone 
• 84319-84-6 (E)-1-Phenyl-3-(toluene-4-sulfonyl)-dodec-1-en-4-ol 

Relevant articles and documents

Barbier/Grignard-type allylation or benzylation mediated by the mischmetall/SmI2(cat.) system

Barbier- and Grignard-type allylation and benzylation have been achieved by the use of samarium diiodide in catalytic amounts together with mischmetall (an alloy of the light lanthanides) as a coreductant. Plausible catalytic schemes are proposed. In addition, organocerium and -lanthanum reagents have been obtained from samarium diiodide catalysed reactions between organic halides and cerium or lanthanum metal, giving a new route to organolanthanoid compounds. It also appears that trivalent benzyl and allyl organometallic compounds of cerium and lanthanum are much more stable than the corresponding samarium ones. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.

α-Lithiomethylenetriphenylphosphorane, a Highly Reactive Ylide Equivalent

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