825629-06-9Relevant academic research and scientific papers
Synthesis and characterization of tributyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1-diazenyl]benzoic acid and 4-[((E)-1-{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1-diazenyl]phenyl}methylidene) amino]aryls - Crystal structures of polymeric (Bu(3)Sn[O (2)CC(6)H(4){NN(C6)(3)-4-OH-5- CHO)}-o])n) and (Bu(3)Sn[O(2)CC(6)H) (4){NN(C(6)H(3)-4-OH(C(H)NC(6)H (4)Cl-4))}-o])(n)
Basu Baul, Tushar S.,Singh, Keisham Surjit,Song, Xueqing,Zapata, Alejandra,Eng, George,Lycka, Antonin,Linden, Anthony
, p. 4702 - 4711 (2004)
The tri-n-butyltin(IV) complexes of 2-[(E)-2-(3-formyl-4-hydroxyphenyl)-1- diazenyl]benzoic acid and 4-[((E)-1-{2-hydroxy-5-[(E)-2-(2-carboxyphenyl)-1- diazenyl]phenyl}methylidene)amino]aryls (aryls = 4-CH3, 4-Br, 4-Cl, 4-OCH3) have been synthesized and characterized by 1H, 13C, 119Sn NMR, IR and 119mSn M?ssbauer spectroscopic techniques in combination with elemental analysis. The crystal structures of two compounds, (Bu3Sn[O2CC6H 4{NN(C6H3-4-OH-5-CHO)}-o])n and (Bu3Sn[O2CC6H4{NN(C 6H3-4-OH(C(H)NC6H4Cl-4))}-o]) n, are reported.The crystallographic and 119Sn M?ssbauer data both indicate that the tributyltin complexes form single-stranded polymeric structures in which the carboxylate O atoms of each aryl ligand bridge two Sn atoms. The Sn atoms have a slighly distorted trigonal bipyramidal coordination geometry with equatorial butyl groups and carboxylate O atoms occupying axial positions. The 119Sn NMR spectroscopic data and the 1J(13C-119/117Sn) coupling constant indicate a tetrahedral coordination geometry in non-coordinating solvents. The results of a toxicity study of a tributyltin compound on the second larval instar of Aedes aegypti mosquito larvae are reported.
