82587-27-7

Upstream product

• 100-46-9 benzylamine 
• 241472-57-1 bis[2-(p-toluenesulfonyloxy)ethyl]diphenylsilane 
• 17937-68-7 diphenyl-divinyl-silane 
• 241472-56-0 2,2'-(diphenylsilylene)bis(ethanol) 
• 772-54-3 N,N-diethylbenzylamine 
• 775-12-2 diphenylsilane 
• 80-10-4 diphenylsilyl dichloride 
• 82587-23-3 Bis-(2-bromethyl)-diphenylsilan 

Downstream Products

• 839677-30-4 2,2,2-trichloroethyl 4,4-diphenyl-4-silapiperidine-1-carboxylate 

Relevant academic research and scientific papers

Consecutive β,β′-Selective C(sp3)?H Silylation of Tertiary Amines with Dihydrosilanes Catalyzed by B(C6F5)3

Tris(pentafluorophenyl)borane has been found to catalyze the two-fold C(sp3)?H silylation of various trialkylamine derivatives with dihydrosilanes, furnishing the corresponding 4-silapiperidines in decent yields. The multi-step reaction cascade involves amine-to-enamine dehydrogenation at two alkyl residues and two electrophilic silylation reactions of those enamines, one inter- and one intramolecular.

4-Silapiperidine and 4-silapiperidinium derivatives: Syntheses and structural characterization

A series of novel 4-silapiperidine and 4-silapiperidinium derivatives, with two silicon-bound aryl groups and various N-organyl groups, have been synthesized and structurally characterized (solution 1H, 13C, 19F, and

Diphenylsilyldiethylene- (DPSide-) group: A new primary amine protection

Diphenylsilydiethylene- (DPSide-) group has been developed as a new primary amine protecting group. The new protecting group exhibits novel orthogonality against other commonly used amine-protecting groups and excellent chemoselectivity for unbranched α-amino acid esters. Removal of this protecting group was effected under mild fluoride-based cleavage conditions.