82644-36-8

Basic information

• Product Name: (6aR)-1,2-dimethoxy-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-3-ol
• Synonyms: 4H-Dibenzo(de,g)quinolin-3-ol, 5,6,6a,7-tetrahydro-1,2-dimethoxy-, (R)-
• CAS NO: 82644-36-8
• Molecular Formula: C₁₈H₁₉NO₃
• Molecular Weight: 297.3484
• Mol File: 82644-36-8.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 480.6°C at 760 mmHg
• Flash Point: 244.5°C
• Density: 1.237g/cm³
• Vapor Pressure: 7.31E-10mmHg at 25°C
• Refractive Index: 1.62
• CAS DataBase Reference: (6aR)-1,2-dimethoxy-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (6aR)-1,2-dimethoxy-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-3-ol(82644-36-8)
• EPA Substance Registry System: (6aR)-1,2-dimethoxy-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinolin-3-ol(82644-36-8)

Safety Data

• Hazardous Substances Data: 82644-36-8(Hazardous Substances Data)

Upstream product

• 6527-13-5 3,4-dimethoxy-(phenylmethoxy)benzaldehyde 
• 1359071-18-3 (R)-1,2-dimethoxy-5,6,6a,7-tetrahydro-6-p-toluenesulfonyl-4H-dibenzo[de,g]quinolin-3-ol 
• 1359071-24-1 (R)-1-(2-bromobenzyl)-6,7-dimethoxy-2-p-toluenesulfonyl-1,2,3,4-tetrahydroisoquinolin-5-ol 
• 1359071-16-1 (R)-1-(2-bromobenzyl)-5-benzyloxy-6,7-dimethoxy-2-p-toluenesulfonyl-1,2,3,4-tetrahydroisoquinoline 
• 1359071-14-9 (+)-1-(2-bromobenzyl)-5-benzyloxy-6,7-dimethoxy-2-p-toluenesulfinyl-1,2,3,4-tetrahydroisoquinoline 
• 1359071-12-7 (R)-N-[2-(2-(benzyloxy)-3,4-dimethoxyphenyl)ethyl]-p-toluenesulfinamide 

Downstream Products

• 41645-66-3 lirinine 
• 41645-66-3 3-Hydroxynuciferin 

Relevant articles and documents

Monoligated Pd(0)-catalyzed intramolecular ortho- and para-arylation of phenols for the synthesis of aporphine alkaloids. Synthesis of (-)-lirinine

An intramolecular palladium(0)-mediated ortho-arylation of phenols applied to the synthesis of various substituted aporphines is reported. Most significantly, the efficiency of the transformation was enhanced by the use of monoligated Pd(0) complexes. This methodology was extended to para-arylation of phenols and employed in the synthesis of the aporphine alkaloid (-)-lirinine.