827307-95-9

Basic information

• Product Name: cis-(4S,5R)-N-(benzylthio)hexahydrobenzoxazolidinone
• Synonyms: cis-(4S,5R)-N-(benzylthio)hexahydrobenzoxazolidinone
• CAS NO: 827307-95-9
• Molecular Weight: 263.36
• Mol File: 827307-95-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-(4S,5R)-N-(benzylthio)hexahydrobenzoxazolidinone(CAS DataBase Reference)
• NIST Chemistry Reference: cis-(4S,5R)-N-(benzylthio)hexahydrobenzoxazolidinone(827307-95-9)
• EPA Substance Registry System: cis-(4S,5R)-N-(benzylthio)hexahydrobenzoxazolidinone(827307-95-9)

Safety Data

• Hazardous Substances Data: 827307-95-9(Hazardous Substances Data)

Upstream product

• 21651-79-6 (3aS,7aR)-3a,4,5,6,7,7a-hexahydrobenzoxazolin-2-one 
• 16601-40-4 S-benzyl phenyl-methanethiosulfonate 

Downstream Products

• 14090-81-4 S-(-)-benzylmethylsulfoxide 
• 827307-99-3 (4S,5R,S_S)-cis-N-(benzylsulfinyl)hexahydrobenzoxazolidin-2-one 

Relevant articles and documents

Cis- and trans-N-(Benzylsulfinyl)hexahydrobenzoxazolidin-2-ones as novel chiral sulfinyl transfer reagents

The synthesis of N-benzylsulfinyl derivatives 5a-d from both pairs of enantiomeric hexahydrobenzoxazolidin-2-ones 4a-d is reported. The use of 5a-d as effective chiral sulfinylating reagents in the preparation of enantiopure sulfoxides (e.e.>98%) is also reported. Graphical Abstract