82736-63-8Relevant academic research and scientific papers
Absolute Rate and Philicity Studies of Methoxyphenylcarbene. An Extended Range for Carbenic Ambiphilicity
Moss, Robert A.,Shen, Shilan,Hadel, Linda M.,Kmiecik-Lawrynovicz, Grazyna,Wlostowska, Joanna,Krogh-Jespersen, Karsten
, p. 4341 - 4349 (1987)
Methoxyphenylcarbene (MeOCPh) was generated by photolysis (-10 deg C) or thermolysis (25, 45 deg C) of 3-methoxy-3-phenyldiazirine and added to six alkenes, affording the corresponding cyclopropanes.The substrates and their relative reactivities toward th
THE EXTRAORDINARY SELECTIVITY OF METHOXYPHENYLCARBENE; THE CASE OF THE CURIOUS " OLEFIN"
Moss, Robert A.,Wlostowska, Joanna
, p. 2559 - 2562 (2007/10/02)
The reaction of MeOCPh with Me2C=CMe2 gives a low yield of the appropriate cyclopropane (3); however, aged olefin containing traces of the related hydroperoxide (8) or alcohol (9) impurities, selectively affords the formal O-H insertion products 7 or 4.
Methoxyphenyldiazirine as Precursor to Methoxyphenylcarbene
Wlostowska, Joanna,Moss, Robert A.,Guo, Wenjeng,Chang, Ming Jing
, p. 432 - 433 (2007/10/02)
Reaction of bromo(phenyl)diazirine (2) with methoxide ion gives methoxy(phenyl)diazirine (3), which yields cyclopropanes (4) on photolysis in alkenes.
