82736-62-7

Upstream product

• 124-41-4 sodium methylate 
• 4222-25-7 3-bromo-3-phenyl-3H-diazirine 

Downstream Products

• 118964-99-1 [Methoxy-(1,1,2-trimethyl-allyloxy)-methyl]-benzene 
• 2236-57-9 Benzaldehyde ethyl methyl acetal 
• 82736-63-8 1-methoxy-1-phenyl-2,2-dimethylcyclopropane 
• 344304-35-4 1-methoxy-1-phenyl-2-cyanocyclopropane 
• 780810-43-7 1-methoxy-1-phenyl-2-carbomethoxycyclopropane 
• 93-58-3 benzoic acid methyl ester 
• 118964-98-0 1-methoxy-2,2,3,3-tetramethyl-1-phenylcyclopropane 
• 1155-16-4 C₁₆H₁₆N₂O₂ 
• 100-52-7 benzaldehyde 
• 59526-67-9 methoxyphenylcarbene 
• 37823-96-4 pentacarbonyl(methoxyphenylmethylene)tungsten⁽⁰⁾ 
• 27436-93-7 pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾ 
• 118965-00-7 [Methoxy-(1,1,2-trimethyl-allylperoxy)-methyl]-benzene 
• 82736-65-0 (1-Methoxy-2,2,3-trimethyl-but-3-enyl)-benzene 

Relevant academic research and scientific papers

Methoxyphenyldiazirine as Precursor to Methoxyphenylcarbene

Reaction of bromo(phenyl)diazirine (2) with methoxide ion gives methoxy(phenyl)diazirine (3), which yields cyclopropanes (4) on photolysis in alkenes.

Nitrenic reactivity of diazirines

Butyl 3-bromo-3H-diazirine-3-carboxylate (7) and 3-bromo-3-phenyl-3H- diazirine (17) exhibit nitrenic reactivity with phenylmagnesium bromide or tetrabutylammonium cyanide. The formation of several N,N′-disubstituted amidines is attributed to the intermediacy of 1-phenyl or 1-cyano-1H-diazirines possessing a singlet imidoylnitrene character at the N2 atom. Most notably, the reaction of 7 with PhMgBr in diethyl ether affords 2-hydroxy-2,2,N- triphenylacetamidine (9) and 2-methyl-5,5-diphenyl-4-phenylamino-2,5- dihydrooxazole (10) as products derived from nitrene insertion to the ether α-C-H bond.

Absolute Rate and Philicity Studies of Methoxyphenylcarbene. An Extended Range for Carbenic Ambiphilicity

Methoxyphenylcarbene (MeOCPh) was generated by photolysis (-10 deg C) or thermolysis (25, 45 deg C) of 3-methoxy-3-phenyldiazirine and added to six alkenes, affording the corresponding cyclopropanes.The substrates and their relative reactivities toward th