82746-16-5Relevant articles and documents
A Metal–Organic Framework with Exceptional Activity for C?H Bond Amination
Wang, Le,Agnew, Douglas W.,Yu, Xiao,Figueroa, Joshua S.,Cohen, Seth M.
, p. 511 - 515 (2018/02/21)
The development of catalysts capable of fast, robust C?H bond amination under mild conditions is an unrealized goal despite substantial progress in the field of C?H activation in recent years. A Mn-based metal–organic framework (CPF-5) is described that promotes the direct amination of C?H bonds with exceptional activity. CPF-5 is capable of functionalizing C?H bonds in an intermolecular fashion with unrivaled catalytic stability producing >105 turnovers.
Yttrium-Catalyzed Intramolecular Hydroalkoxylation/Claisen Rearrangement Sequence: Efficient Synthesis of Medium-Sized Lactams
Zhou, Bo,Li, Long,Zhu, Xin-Qi,Yan, Juan-Zhu,Guo, Yi-Lin,Ye, Long-Wu
supporting information, p. 4015 - 4019 (2017/03/27)
An efficient yttrium-catalyzed intramolecular hydroalkoxylation/Claisen rearrangement sequence has been achieved, thus enabling facile access to a diverse array of valuable medium-sized lactams. Furthermore, a mechanistic rationale for this novel cascade
Efficient photolytic C-H bond functionalization of alkylbenzene with hypervalent iodine(iii) reagent
Sakamoto, Ryu,Inada, Tsubasa,Selvakumar, Sermadurai,Moteki, Shin A.,Maruoka, Keiji
supporting information, p. 3758 - 3761 (2016/03/25)
A practical approach to radical C-H bond functionalization by the photolysis of a hypervalent iodine(iii) reagent is presented. The photolysis of [bis(trifluoroacetoxy)iodo]benzene (PIFA) leads to the generation of trifluoroacetoxy radicals, which allows the smooth transformation of various alkylbenzenes to the corresponding benzyl ester compounds under mild reaction conditions.
