82754-32-3Relevant academic research and scientific papers
Stereoselective synthesis of (E)-β-fluoro-α,β-unsaturated esters by carbonylation of (E)-2-fluoro-1-iodo-1-alkenyliodonium salts
Hara, Shoji,Yamamoto, Kenichi,Yoshida, Masanori,Fukuhara, Tsuyoshi,Yoneda, Norihiko
, p. 7815 - 7818 (2007/10/03)
(E)-β-Fluoro-α,β-unsaturated esters were stereoselectively obtained by the palladium-catalyzed carbonylation reaction of (E)-2-fluoro-1-iodo-1-alkenyliodonium salts obtained by the addition of iodotoluene difluoride to 1-alkynes.
Mono-hydrofluorination of Electrophilic Alkynes by the Liquid Bishasic CsF-H2O-DMF System (DMF = N,N-dimethylformamide)
Gorgues, Alain,Stephan, Dominique,Cousseau, Jack
, p. 1493 - 1494 (2007/10/02)
CsF induces the addition of HF in fair yields to activated acetylenic triple bonds in a DMF-water bishasic medium (DMF = N,N-dimethylformamide); in a homogeneous DMF-water mixture, no addition is observed.
Tetrabutylammonium and polymer-supported dihydrogentrifluoride: new reagents for the hydrofluorination of activated acetylenic bonds
Cousseau, Jack,Albert, Patrice
, p. 910 - 915 (2007/10/02)
Tetrabutylammonium and polymer-supported dihydrogentrifluoride are easily prepared by a phase-transfer procedure from the corresponding fluoride salts.These stable new dihydrogentrifluoride salts allow the addition of HF under mild conditions to carbon-ca
Tetrabutylammonium and Polymer-supported Dihydrogentrifluoride: New Hydrofluorinating Reagents for Electrophilic Alkynes
Albert, Patrice,Cousseau, Jack
, p. 961 - 962 (2007/10/02)
Tetrabutylammonium and polymer-supported dihydrogentrifluoride are readily accessible reagents which allow addition of HF to activated carbon-carbon triple bonds, thus leading to functional fluoroalkenes in good yields.
