827609-58-5

Upstream product

• 1666-13-3 diphenyl diselenide 
• 827609-57-4 (6S,12bR)-12-(tert-butoxycarbonyl)-1,2,3,4,6,7,12,12b-octahydro-4-oxoindolo[2,3-a]quinolizine-6-carboxylic acid 
• 154-09-6 L-tryptophanol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 6026-86-4 methyl 4-formylbutanoate 
• 827609-56-3 (6S,12bR)-tert-butyl-6-formyl-1,2,3,4,6,7-hexahydro-4-oxoindolo[2,3-a]quinolizine-12(12bH)-carboxylate 
• 827609-55-2 (6S,12bR)-4-oxo-1,2,3,4,6,7,12,12b-octahydropyrido[2,1-a]β-carboline-6-carbaldehyde 
• 778591-55-2 (6S,12bR)-1,2,3,6,7,12b-hexahydro-6-(hydroxymethyl)indolo[2,3-a]quinolizin-4(12H)-one 
• 546128-82-9 (3S,8aS)-3-([1H-indol-3-yl]methyl)hexahydrooxazolo[3,2-a][1,3]pyridin-5-one 

Downstream Products

• 74559-69-6 (R)-(+)-deplancheine 

Relevant academic research and scientific papers

A new asymmetric synthesis of (+)-12b-epidevinylantirhine

We report a new asymmetric synthesis of the indole alkaloid derivative (+)-12b-epidevinylantirhine through stereoselective cyclization of a tethered indole nucleus onto an N-acyliminium ion intermediate, generated from a readily available non-racemic bicy

Complementary stereoselective conjugate addition reactions on indolo[2,3-a]quinolizine templates

We report a new and highly stereoselective approach for the construction of a range of functionalized indolo[2,3-a]quinolizine targets from a readily available, nonracemic chiral template. The methods developed allow us to predetermine relative product st

A highly stereoselective synthesis of the indolo[2,3-a]quinolizine ring system and application to natural product synthesis

We present a facile and highly stereoselective approach to the indolo[2,3-a]quinolizine ring system from a readily available, non-racemic chiral template. We demonstrate the potential for application of this methodology to natural product synthesis throug

An asymmetric synthesis of both enantiomers of the indole alkaloid deplancheine

(Chemical Equation Presented). We report a novel, facile and asymmetric approach to both enantiomers of the indole alkaloid deplancheine from a readily available, nonracemic chiral template. The natural product and its antipode are isolated with >95% ee.