82769-47-9Relevant articles and documents
Ruthenium-catalyzed oxidation of tertiary amines with hydrogen peroxide in the presence of methanol
Murahashi, Shun-Ichi,Naota, Takeshi,Miyaguchi, Noriko,Nakato, Takeshi
, p. 6991 - 6994 (1992)
α-Methoxylation of tertiary amines can be performed by the ruthenium-catalyzed oxidation of tertiary amines with hydrogen peroxide in the presence of methanol. The reaction provides an efficient method for selective N-demethylation of tertiary methylamines and construction of quinoline skeletons.
Cyanomethylamines and azidomethylamines: new general methods of the synthesis and transformations
Nabiev, Orudzh G.,Nabizade, Zargalam O.,Kostyanovsky, Remir G.
body text, p. 281 - 283 (2010/01/18)
Simple and efficient methods have been developed to obtain cyanomethylamines and azidomethylamines using reactions of methoxymethylamines with TMSCN and TMSN3, respectively. In the case of dimethylformamide dimethylacetal, only one MeO group wa