82769-47-9

Basic information

• Product Name: N-ethyl-N-(methoxymethyl)aniline
• Synonyms: N-ethyl-N-(methoxymethyl)aniline
• CAS NO: 82769-47-9
• Molecular Weight: 165.235
• Mol File: 82769-47-9.mol

Chemical Properties

• CAS DataBase Reference: N-ethyl-N-(methoxymethyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-ethyl-N-(methoxymethyl)aniline(82769-47-9)
• EPA Substance Registry System: N-ethyl-N-(methoxymethyl)aniline(82769-47-9)

Safety Data

• Hazardous Substances Data: 82769-47-9(Hazardous Substances Data)

Upstream product

• 103-69-5 N-ethyl-N-phenylamine 
• 67-56-1 methanol 
• 50-00-0 formaldehyd 
• 147676-24-2 N-ethyl-N-<(benzotriazol-1-yl)methyl>aniline 
• 613-97-8 N-methyl-N-ethylaniline 

Downstream Products

• 1209493-92-4 C₉H₁₂N₄ 
• 103-69-5 N-ethyl-N-phenylamine 

Relevant articles and documents

Ruthenium-catalyzed oxidation of tertiary amines with hydrogen peroxide in the presence of methanol

α-Methoxylation of tertiary amines can be performed by the ruthenium-catalyzed oxidation of tertiary amines with hydrogen peroxide in the presence of methanol. The reaction provides an efficient method for selective N-demethylation of tertiary methylamines and construction of quinoline skeletons.

One-Pot Synthesis of α-Halo β-Amino Acid Derivatives via the Difunctional Coupling of Ethyl α-Diazoacetate with Silyl Halides and N, O -Acetals or Aromatic Tertiary Amines

The difunctionalization of ethyl α-diazoacetate (EDA) using silyl halides as a nucleophile and N, O -acetals as an electrophile under metal-free conditions is described. This process undergoes a novel three-component coupling (3-CC) reaction using EDA, which leads to a one-pot preparation of α-halo β-amino acid esters. Also, this protocol could be adapted to accept an electrophile composed of aromatic tertiary amines. In both 3-CC reactions, the key reaction intermediate is an iminium intermediate that can be easily and effectively generated either from N, O -acetals or from aromatic tertiary amines.

Cyanomethylamines and azidomethylamines: new general methods of the synthesis and transformations

Simple and efficient methods have been developed to obtain cyanomethylamines and azidomethylamines using reactions of methoxymethylamines with TMSCN and TMSN3, respectively. In the case of dimethylformamide dimethylacetal, only one MeO group wa

A convenient synthesis of N-(α-alkoxyalkyl)- and N-[α-(alkylthio)alkyl]amines

Aminoalkylation of alcohols and of thiols by N-[1-(benzotriazol-1-yl)alkyl]amines under mild conditions give N-(α-alkoxyalkyl)amines 2 and N-[α-(alkylthio)alkyl]amines 3, respectively, in good yields.