82772-05-2Relevant articles and documents
A New Synthesis of 3-Amino-2-alkenoates. Novel Synthetic Route to Amino Sugars N-benzoyl-L-daunosamine and -L-acosamine
Hiyama, Tamejiro,Kobayashi, Kazuhiro,Nishide, Kiyoharu
, p. 2127 - 2138 (1987)
Alkanoate esters are found to couple with various nitriles to give (Z)-3-amino-2-alkenoates in good yields with the aid of a magnesium amide prepared by the reaction of ethylmagnesium bromide and diisopropylamine.The C-C bond forming reaction was applied
A NEW SYNTHESIS OF 3-AMINO-2-ALKENOATES
Hiyama, Tamejiro,Kobayashi, Kazuhiro
, p. 1597 - 1600 (2007/10/02)
Magnesium enolates of t-butyl (or ethyl) acetate and t-butyl propionate are found to react with nitriles to gives 3-amino-2-alkenoates having Z configuration.