82777-09-1Relevant articles and documents
Synthesis of diiodinated biphenyls and iodinated meta-terphenyls by regioselective Suzuki-Miyaura cross-coupling reactions of 5-substituted 1,2,3-triiodobenzenes
Al-Zoubi, Raed M.,Al-Jammal, Walid K.,El-Khateeb, Mohammad Y.,McDonald, Robert
, p. 3374 - 3384 (2015)
A variety of 2,3-diiodinated biphenyl and iodinated meta-terphenyl derivatives were synthesized by a regioselective Suzuki-Miyaura cross-coupling reaction of 5-substituted 1,2,3-triiodobenzenes. By using 1 equiv. of arylboronic acid, the Suzuki-Miyaura re
Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Nickel(II) Catalyst
Wang, Chaoqun,Kang, Xiaohui,Dai, Shengyu,Cui, Fengchao,Li, Yunqi,Mu, Hongliang,Mecking, Stefan,Jian, Zhongbao
, p. 4018 - 4022 (2020/12/25)
An effective shielding of both apical positions of a neutral NiII active site is achieved by dibenzosuberyl groups, both attached via the same donors’ N-aryl group in a Cs-type arrangement. The key aniline building block is accessibl
Ir-catalyzed synthesis of substituted tribenzosilepins by dehydrogenative C-H/Si-H coupling
Shibata, Takanori,Uno, Ninna,Sasaki, Tomoya,Takano, Hideaki,Sato, Tatsuki,Kanyiva, Kyalo Stephen
, p. 3426 - 3432 (2018/04/14)
The Ir-catalyzed intramolecular reaction of 2′,6′-diaryl-2-(hydrosilyl)biphenyls gave substituted tribenzosilepins by direct dehydrogenative C-H/Si-H coupling. This is the first example of catalytic construction of the tribenzosilepin skeleton. Enantiomer
