82777-35-3

Basic information

• Product Name: 5-(phenylsulfonyl)pentyl 4-methylbenzenesulfonate
• Synonyms: 5-(phenylsulfonyl)pentyl 4-methylbenzenesulfonate
• CAS NO: 82777-35-3
• Molecular Weight: 382.502
• Mol File: 82777-35-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-(phenylsulfonyl)pentyl 4-methylbenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(phenylsulfonyl)pentyl 4-methylbenzenesulfonate(82777-35-3)
• EPA Substance Registry System: 5-(phenylsulfonyl)pentyl 4-methylbenzenesulfonate(82777-35-3)

Safety Data

• Hazardous Substances Data: 82777-35-3(Hazardous Substances Data)

Upstream product

• 19300-54-0 toluene-4-sulfonic acid pent-4-enyl ester 
• 873-55-2 sodium benzenesulfonate 
• 20395-28-2 5-chloropentyl acetate 
• 82777-38-6 5-phenylsulfonyl-1-pentanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 82777-34-2 Acetic acid 5-benzenesulfonyl-pentyl ester 
• 82777-33-1 5-(phenylthio)pentyl acetate 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 82777-39-7 1-ethoxy-5-phenylsulphonylpentane 

Relevant articles and documents

Hydrosulfonylation of Unactivated Alkenes by Visible Light Photoredox Catalysis

The anti-Markovnikov hydrosulfonylation of unactivated alkenes with sodium sulfinates was realized via [Ir(dF(CF3)ppy)2(dtbbpy)]PF6-mediated visible light photoredox catalysis. The presence of an acid such as acetic acid is essential for the reaction to take place. A variety of unactivated alkenes can be transformed into sulfones with good yield and high regioselectivity using this reaction, which is proposed to proceed by a radical mechanism.