828246-57-7Relevant academic research and scientific papers
Synthesis of highly functionalised enantiopure bicyclo[3.2.1]-octane systems from carvone
Abad, Antonio,Agullo, Consuelo,Cunat, Ana C.,De Alfonso, Ignacio,Navarro, Ismael,Vera, Noelia
, p. 287 - 299 (2007/10/03)
The commercially available monoterpene carvone has been efficiently converted into the tricyclo[3.2.1.02.7]octane and bicyclo[3.2.1]octane systems characteristic of some biologically active compounds. The sequence used for this transformation involves as key features an intramolecular Diels-Alder reaction of a 5-vinyl-1,3-cyclohexadiene and a cyclopropane ring opening.
