82829-24-1 Usage
Uses
Used in Pharmaceutical Industry:
Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium is used as a catalyst for the synthesis of various pharmaceutical compounds. Its ability to promote efficient and selective transformations of substrates enables the production of complex molecules with high yields and selectivity, which is crucial for the development of new drugs and the improvement of existing ones.
Used in Agrochemical Industry:
In the agrochemical industry, Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium is employed as a catalyst for the synthesis of agrochemicals, such as pesticides and herbicides. Its selectivity and efficiency in catalyzing organic reactions contribute to the development of more effective and environmentally friendly agrochemicals.
Used in Fine Chemicals Industry:
Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium is used as a catalyst in the synthesis of fine chemicals, which are high-purity chemicals used in various applications, including fragrances, dyes, and specialty chemicals. Its ability to catalyze complex reactions with high selectivity makes it an essential tool in the production of these high-value chemicals.
Used in Organometallic Chemistry Research:
Due to its unique structure and reactivity, Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium is a target of interest for researchers in the field of organometallic chemistry. It is used as a model compound to study the fundamental properties of organometallic complexes and to explore new catalytic systems and reaction mechanisms.
Used in Asymmetric Synthesis:
Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium is used as a catalyst in asymmetric synthesis, a branch of organic chemistry that focuses on the production of chiral compounds with a single enantiomer. Its ability to selectively catalyze reactions to produce enantiomerically pure products is highly valuable in the synthesis of biologically active compounds, such as pharmaceuticals and agrochemicals.
Check Digit Verification of cas no
The CAS Registry Mumber 82829-24-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,8,2 and 9 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 82829-24:
(7*8)+(6*2)+(5*8)+(4*2)+(3*9)+(2*2)+(1*4)=151
151 % 10 = 1
So 82829-24-1 is a valid CAS Registry Number.
82829-24-1Relevant articles and documents
P-H activation of secondary phosphanes on a parent amido diiridium complex
Mena, Inmaculada,Casado, Miguel A.,Polo, Victor,Garcia-Orduna, Pilar,Lahoz, Fernando J.,Oro, Luis A.
supporting information, p. 1609 - 1619 (2014/01/06)
Selected secondary phosphanes (H-PR2; R = Ph, Cy, iPr) smoothly react with a parent amido-bridged diiridium cyclooctadiene complex affording mixed amido/(bis)phosphido dinuclear species. A careful investigation of the reaction profile, carried out by experimental and theoretical tools, revealed that, after an initial amido/phosphido exchange, at low temperatures a second molecule of secondary phosphane adds to the dinuclear system through an oxidative addition process leading to a hydrido amido/bis(phosphido) mixed-valence complex [IrIII/IrI]. These species rearrange above -10 °C into the most stable isomer that arises from a migration of the hydrido moiety to one of the CH fragments of a coordinated cod molecule, a transformation facilitated by the formation of an intermetallic bond. Further heating of these species reductively eliminates ammonia affording bis(phosphido)-metal-metal bonded complexes. The Royal Society of Chemistry.
Niobium/rhodium bimetallic complexes: synthesis, structure, and catalytic hydrosilylation of acetophenone and benzaldehyde
Leelasubcharoen, Somying,Zhizhko, Pavel A.,Kuzmina, Lyudmila G.,Churakov, Andrei V.,Howard, Judith A. K.,Nikonov, Georgii I.
, p. 4500 - 4506 (2009/12/06)
Reactions of a new imido phosphido complex, Cp2Nb(=NBu t)(PPh2) (1), with olefin complexes of rhodium afford two types of compounds. With [(μ-C1)Rh(C2H4) 2]2, an imido/phosphido-
