82843-80-9

Upstream product

• 127654-94-8 C₂₅H₃₅N₂O₆P 
• 82843-81-0 (-)-carinatone 
• 82843-84-3 2,3-dihydrobenzofuran 
• 39985-14-3 2-[2-(3,4-dimethoxy-phenyl)-1-methyl-ethyl]-6-methoxy-4-propyl-phenol 
• 2150-38-1 methyl 3,4-dimethoxybenzoate 
• 127654-91-5 4-Allyl-2-methoxyphenyl N,N,N',N'-tetramethylphosphorodiamidate 
• 127654-92-6 4-Allyl-2-methoxy-6-methylphenyl N,N,N',N'-tetramethylphosphorodiamidate 
• 127654-93-7 4-Allyl-2-ethyl-6-methoxyphenyl N,N,N',N'-tetramethylphosphorodiamidate 
• 97-53-0 4-allylguaiacol 
• 1607447-04-0 6-vinyleugenol 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 1234973-96-6 C₂₁H₂₄O₅ 
• 22934-51-6 5-allyl-2-hydroxy-3-methoxybenzaldehyde 

Relevant academic research and scientific papers

THE NEOLIGNANS (-)-CARINATONE AND CARINATIN FROM VIROLA CARINATA

From the bark of Virola carinata two neolignans have been isolated: (-)-carinatone, and carinatin, .Key Word

Substrate-directed hydroacylation: Rhodium-catalyzed coupling of vinylphenols and nonchelating aldehydes

We report a protocol for the hydroacylation of vinylphenols with aryl, alkenyl, and alkyl aldehydes to form branched products with high selectivity. This cross-coupling yields α-aryl ketones that can be cyclized to benzofurans, and it enables access to eu

LITHIATION OF ORTHO-TOLYL TETRAMETHYLPHOSPHORODIAMIDATES: A FACILE SYNTHESIS OF 2- ARYLBENZOFURANS INCLUDING NEOLIGNAN, CARINATIN

ortho-Tolyl tetramethylphosphorodiamidates were lithiated with sec-BuLi at -105 deg C to give corresponding benzylic lithio species which underwent reaction with electrophiles.When benzoates were used as electrophiles, deoxybenzoin derivatives were obtain