82847-39-0Relevant academic research and scientific papers
Synthesis of Binuclear and Trinuclear Cluster Halides of Molybdenum and Rhenium, and of Carbonyl Halides of Rhenium, Iridium, Ruthenium, and Platinum using Metal Atoms
Brown, Paul R.,Cloke, F. Geoffrey,Green, Malcolm L. H.,Tovey, Robert C.
, p. 519 - 520 (1982)
Reactive halocarbons such as 1,2-dibromo- (or dichloro-) ethane or allyl chloride will halogenate atoms of molybdenum and rhenium under co-condensation conditions giving solvated transition metal halides in lower valence states, e.g. (THF = tetrahydrofuran), which are useful synthetic precursors; co-condensation of rhenium with oxalyl chloride gives 2, ruthenium atoms when co-condensed with oxalyl chloride give a carbonyl halide compound which adds trimethylphosphine forming , and similarly, iridium atoms with oxalyl chloride and then triphenylphosphine give .
