82854-95-3Relevant academic research and scientific papers
New Modes of Bonding in Some Platinum Derivatives of B18H22: X-Ray Crystal Structures of and of Three Structural Isomers of
Cheek, Yvonne M.,Greenwood, Norman N.,Kennedy, John D.,McDonald, Walter S.
, p. 80 - 81 (1982)
Reaction of the deprotonated anti-isomer of B18H22 with cis- yields 4-anti-B18H20)(PMe2Ph)2>> a novel μ-η1, η2 isomer in which the Pt(PMe2Ph)2 group bridges the two edge-linked B10 clusters, together with a more compact green diplatina derivative in which the novel confacial conjuncto-borane unit B18H16 is η4-bonded to one Pt(PMe2Ph)2 unit and (η4 + η2)-bonded to the other; use of syn-B18H22 provides a third isomer of .
