Journal of the Chemical Society. Chemical communications p. 80 - 81 (1982)
Update date:2022-08-04
Topics: X-ray crystal structures Coordination Compound Structural isomers
Cheek, Yvonne M.
Greenwood, Norman N.
Kennedy, John D.
McDonald, Walter S.
Reaction of the deprotonated anti-isomer of B18H22 with cis-a novel μ-η1, η2 isomer in which the Pt(PMe2Ph)2 group bridges the two edge-linked B10 clusters, together with a more compact green diplatina derivative <(Pt2B18H16)(PMe2Ph)4> in which the novel confacial conjuncto-borane unit B18H16 is η4-bonded to one Pt(PMe2Ph)2 unit and (η4 + η2)-bonded to the other; use of syn-B18H22 provides a third isomer of <(PtB18H20)(PMe2Ph)2>.
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