82871-47-4Relevant academic research and scientific papers
Triarylcarbenium Salts Highly Reducible by Primary Alcohols
Wada, Masanori,Mishima, Hisashi,Watanabe, Tetsuya,Natsume, Satoko,Konishi, Hideki,et al.
, p. 1462 - 1463 (1993)
The carbenium salts 2C>X (X = ClO4, BF4), prepared from Ph2COH and a slight excess of acid in propan-2-ol, have been reduced in primary alcohol or methanol much faster than the related triarylcarbenium salts to give Ph2CH and the aldehyde.
Protonation of Stable ? Carbocations. Requirements for the Reaction of Two Positively Charged Species with Each Other in Solution
Smith, Robert J.,Miller, Theresa Moore,Pagni, Richard M.
, p. 4181 - 4188 (2007/10/02)
The trityl ion 5 undergoes a very rapid exchange reaction (Hm >> Hp) with protons in CF3SO3H at temperatures as low as -40 deg C.Reasons are offered why this nonplanar ion is protonated so rapidly.The 1H NMR spectra of the phenalenyl
