Triarylcarbenium Salts Highly Reducible by Primary Alcohols

DOI: 10.1039/c39930001462

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1462 - 1463 (1993)

Update date:2022-08-04

Topics:

Authors:

Wada, Masanori

Mishima, Hisashi

Watanabe, Tetsuya

Natsume, Satoko

Konishi, Hideki

et al. et al.

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Article abstract of DOI:10.1039/c39930001462

The carbenium salts 2C>X (X = ClO4, BF4), prepared from Ph<2,6-(MeO)2C6H3>2COH and a slight excess of acid in propan-2-ol, have been reduced in primary alcohol or methanol much faster than the related triarylcarbenium salts to give Ph<2,6-(MeO)2C6H3>2CH and the aldehyde.

Full text of DOI:10.1039/c39930001462

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