82877-25-6Relevant academic research and scientific papers
Cleavage of Si-C and Ge-C bonds in heterylsilanes and -germanes by organolithium reagents
Gevorgyan, Vladimir,Borisova, Larisa,Lukevics, Edmunds
, p. 381 - 387 (1992)
Organolithium reagents RLi can cleave Si-C and Ge-C bonds in heterylsilanes and -germanes substituting furyl, dihydrofuryl and dihydropyranyl groups for the organolithium residue R.
CONVERSIONS OF -SILANES AND -GERMANES UNDER CATALYTIC HYDROGENATION CONDITIONS
Lukevics, E.,Gevorgyan, V. N.,Goldberg, Y. S.,Shymanska, M. V.
, p. 163 - 172 (2007/10/02)
(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of trimethylsilane (I), bisdimethylsilane (II) and trimethylgermane with a Pd/Al2O3 catalyst.The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.
