128756-77-4Relevant academic research and scientific papers
Collective Total Synthesis of Casbane Diterpenes: One Strategy, Multiple Targets
L?ffler, Lorenz E.,Wirtz, Conny,Fürstner, Alois
, p. 5316 - 5322 (2021)
Of the more than 100 casbane diterpenes known to date, only the eponymous parent hydrocarbon casbene itself has ever been targeted by chemical synthesis. Outlined herein is a conceptually new approach that brings not a single but a variety of casbane deri
Cleavage of Si-C and Ge-C bonds in heterylsilanes and -germanes by organolithium reagents
Gevorgyan, Vladimir,Borisova, Larisa,Lukevics, Edmunds
, p. 381 - 387 (2007/10/02)
Organolithium reagents RLi can cleave Si-C and Ge-C bonds in heterylsilanes and -germanes substituting furyl, dihydrofuryl and dihydropyranyl groups for the organolithium residue R.
Reaction of heteryl-silanes and -germanes with metal hydrides
Gevorgyan, Vladimir,Borisova, Larisa,Lukevics, Edmunds
, p. 57 - 67 (2007/10/02)
A series of heteryl-silanes and germanes containing a different number of dihydrofuryl and dihydropyranyl groups at the metal atom has been obtained by the means of the lithium synthesis.Subsequent substitution of heteryl group for hydride ion occurs duri
