82880-44-2Relevant academic research and scientific papers
Facile Cu(I)-catalyzed oxidative coupling of anilines to azo compounds and hydrazines with diaziridinone under mild conditions
Zhu, Yingguang,Shi, Yian
supporting information, p. 1942 - 1945 (2013/06/04)
A mild and highly efficient Cu(I)-catalyzed oxidative coupling of anilines is described. Various primary and secondary anilines can be efficiently coupled under mild conditions to the corresponding azo compounds and hydrazines in high yields. This method provides a direct and practical access to these compounds and is also amenable to gram scale with no special precautions to exclude air or moisture.
Photocleavage of Diarylnitrosamines in Neutral Media
Crumrine, David S.,Brodbeck, Charles M.,Dombrowski, Paul H.,Haberkamp, Thomas J.,Kekstas, Rita J.,et al.
, p. 4246 - 4249 (2007/10/02)
N-Nitrosodiphenylamine, N-nitroso(2-nitrophenyl)phenylamine, N-nitroso(3-methylphenyl)phenylamine, and N-nitrosocarbazole were irradiated in degassed neutral solution to give the corresponding diarylamine as the initial photoproduct.The effects of changing solvents, concentrations, and substituents and of adding catalysts were examined.Quantum yield studies, sensitization work, and ESR studies were used to study the mechanism of this photolysis.
