1205-64-7

Basic information

• Product Name: 3-Methyldiphenylamine
• Synonyms: N-(3-Methylphenyl)benzenamine;Phenyl(3-methylphenyl)amine;3-Methyldiphenylamine,98%;3-two Methylaniline;1-phenyl-2-(m-tolyl)hydrazine;3-methyl-n-phenyl-benzenamin;N-PHENYL-N-M-TOLYL-AMINE;N-PHENYL-M-TOLUIDINE
• CAS NO: 1205-64-7
• Molecular Formula: C₁₃H₁₃N
• Molecular Weight: 183.25
• EINECS: 214-885-8
• Product Categories: electronic;Amines;Electronic Chemicals;C11 to C38;Nitrogen Compounds
• Mol File: 1205-64-7.mol
• Article Data: 75

Chemical Properties

• Melting Point: 30 °C
• Boiling Point: 315 °C724 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: yellow liquid or crystal
• Density: 1.066 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.000389mmHg at 25°C
• Refractive Index: n20/D 1.635(lit.)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 0.97±0.30(Predicted)
• CAS DataBase Reference: 3-Methyldiphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyldiphenylamine(1205-64-7)
• EPA Substance Registry System: 3-Methyldiphenylamine(1205-64-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• TSCA: Yes
• Hazardous Substances Data: 1205-64-7(Hazardous Substances Data)

Usage

Chemical Properties

brown to black liquid after melting

InChI:InChI=1/C13H13N/c1-11-6-5-9-13(10-11)14-12-7-3-2-4-8-12/h2-10,14H,1H3

Upstream product

• 14152-08-0 5-Anilino-3-oxy-1-methyl-benzol 
• 108-86-1 bromobenzene 
• 108-44-1 1-amino-3-methylbenzene 
• 537-92-8 3-Methylacetanilide 
• 73333-80-9 N-(3-Methylphenyl)-N-phenylbenzamide 
• 591-17-3 meta-bromotoluene 
• 62-53-3 aniline 
• 502630-89-9 2-(3-chloro-5-methylphenyl)-4,4,5,5-tetra methyl-1,3,2-dioxaborolane 
• 106-39-8 bromochlorobenzene 
• 13716-12-6 tri-tert-butyl phosphine 
• 3375-31-3 palladium diacetate 
• 35692-20-7 trimethoxy(m-tolyl)silane 
• 108-39-4 3-methyl-phenol 
• 98-80-6 phenylboronic acid 

Downstream Products

• 124729-98-2 4,4′,4″-tris[3-methylphenyl(phenyl)amino]triphenylamine 
• 3652-91-3 2-methyl-9H-carbazole 
• 82880-43-1 N-nitroso(3-methylphenyl)phenylamine 
• 82880-44-2 N,N'-diphenyl-N,N'-bis(3-methylphenyl)hydrazine 
• 110700-05-5 2-Brom-N-phenyl-N-(m-tolyl)acetamid 
• 152700-50-0 N-(3-methylphenyl)-N-phenyl-N-(prop-2-ynyl)amine 
• 65181-78-4 4,4'-bis(m-tolylphenylamino)biphenyl 
• 117-65-7 Methylpromazin 
• 890715-10-3 [2-[(3-methylphenyl)(phenyl)amino]-2-oxoethyl]carbamic acid benzyl ester 
• 177535-24-9 2',3',6'-Trifluorophenyl 1,10-dimethylacridan-9-carboxylate 
• 80223-29-6 N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,4-phenylenediamine 
• 4316-54-5 N,N-diphenyl-m-toluidine 
• 76656-51-4 N,N'-diphenyl-N,N'-bis[3-methylphenyl]-pyrenyl-1,6-diamine 

Related news

A theoretical and experimental investigation of vibrational spectra and electronic transitions on 3-Methyldiphenylamine (cas 1205-64-7) molecule as organic semiconductor07/18/2019

In this study, the structural and spectroscopic investigations of 3-methyldiphenylamine were reported. The molecular geometry was optimized from Density Functional Theory (B3LYP method) using 6-31+G(d,p) basis set on the ground state and the infrared wavenumbers and intensities were predicted by...detailed

Relevant articles and documents

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In Situ Formation of Cationic π-Allylpalladium Precatalysts in Alcoholic Solvents: Application to C-N Bond Formation

We report an efficient Buchwald-Hartwig cross-coupling reaction in alcoholic solvent, in which a low catalyst loading showed excellent performance for coupling aryl halides (I, Br, and Cl) with a broad set of amines, amides, ureas, and carbamates under mild conditions. Mechanistically speaking, in a protic and polar medium, extremely bulky biarylphosphine ligands interact with the dimeric precatalyst [Pd(π-(R)-allyl)Cl]2 to form the corresponding cationic complexes [Pd(π-(R)-allyl)(L)]Cl in situ and spontaneously. The resulting precatalyst further evolves under basic conditions into the corresponding L-Pd(0) catalyst, which is commonly employed for cross-coupling reactions. This mechanistic study highlights the prominent role of alcoholic solvents for the formation of the active catalyst.

Nickel-Catalyzed Amination of Aryl Nitriles for Accessing Diarylamines through C?CN Bond Activation

A nickel-catalyzed amination to access diarylamines has been developed through C?CN bond activation of aryl nitriles with anilines. In this developed catalytic protocol, various aromatic and heteroaromatic nitriles could be utilized as the electrophiles to couple with substituted anilines. A diversity of diarylamines were obtained in 15–95% yields. (Figure presented.).

Nickel-Catalyzed Amination of Aryl Thioethers: A Combined Synthetic and Mechanistic Study

Herein, we report a nickel-1,2-bis(dicyclohexylphosphino)ethane (dcype) complex for the catalytic Buchwald-Hartwig amination of aryl thioethers. The protocol shows broad applicability with a variety of different functional groups tolerated under the catalytic conditions. Extensive organometallic and kinetic studies support a nickel(0)-nickel(II) pathway for this transformation and revealed the oxidative addition complex as the resting state of the catalytic cycle. All the isolated intermediates have proven to be catalytically and kinetically competent catalysts for this transformation. The fleeting transmetalation intermediate has been successfully synthesized through an alternative synthetic organometallic pathway at lower temperature, allowing for in situ NMR study of the C-N bond reductive elimination step. This study addresses key factors governing the mechanism of the nickel-catalyzed Buchwald-Hartwig amination process, thus improving the understanding of this important class of reactions.