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METHYL (2-METHYL-3-TRIMETHYLSILOXYCYCLOPROPANE-CARBOXYLATE) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

82884-40-0

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82884-40-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 82884-40-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,2,8,8 and 4 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 82884-40:
(7*8)+(6*2)+(5*8)+(4*8)+(3*4)+(2*4)+(1*0)=160
160 % 10 = 0
So 82884-40-0 is a valid CAS Registry Number.

82884-40-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl 2-methyl-3-trimethylsilyloxycyclopropane-1-carboxylate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:82884-40-0 SDS

82884-40-0Relevant academic research and scientific papers

ENANTIOSELECTIVE SYNTHESIS OF SILOXYCYCLOPROPANES AND OF γ-OXOCARBOXYLATES BY ASYMMETRIC CATALYSIS

Kunz, Thomas,Reissig, Hans-Ulrich

, p. 2079 - 2082 (2007/10/02)

Up to 48percent enantiomeric excess have been attained by cyclopropanation of silyl enol ethers with methyl diazoacetate in the presence of optically active Cu-catalysts.Subsequent ring opening of resulting siloxycyclopropanes gives γ-oxocarboxylates with

Synthesis of 2-Siloxy-substituted Methyl Cyclopropanecarboxylates

Kunkel, Elisabeth,Reichelt, Ingrid,Reissig, Hans-Ulrich

, p. 512 - 530 (2007/10/02)

2-Siloxy-substituted methyl cyclopropanecarboxylates C - useful building blocks in synthesis - are obtained in great variety and with good yields from the silyl enol ethers E and methyl diazoacetate (D) under copper salt catalysis.Whereas the regiochemical and stereochemical properties of E are completely transferred to the cyclopropanes C, the stereoselectivity concerning the position of the methoxycarbonyl group is low.The 1H and 13C data used to determine the configurations of compounds C are discussed.

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