82892-10-2

Basic information

• Product Name: anti-1-(1,3-dioxolan-2-yl)-3-(p-nitrophenyl)-propanone oxime
• CAS NO: 82892-10-2
• Molecular Weight: 266.254
• Mol File: 82892-10-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: anti-1-(1,3-dioxolan-2-yl)-3-(p-nitrophenyl)-propanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: anti-1-(1,3-dioxolan-2-yl)-3-(p-nitrophenyl)-propanone oxime(82892-10-2)
• EPA Substance Registry System: anti-1-(1,3-dioxolan-2-yl)-3-(p-nitrophenyl)-propanone oxime(82892-10-2)

Safety Data

• Hazardous Substances Data: 82892-10-2(Hazardous Substances Data)

Upstream product

• 100-14-1 4-nitrobenzyl chloride 
• 82902-22-5 C₅H₈LiNO₄ 

Relevant articles and documents

α-Nitro Ketones and Esters from Acylimidazoles

The anion of 2-(2-nitroethyl)-1,3-dioxolane (4), prepared from the corresponding 2-bromo compound (3), undergoes condensation with acylimidazoles to give the 3-nitro-4-oxobutanal acetals (9), which can serve as valuable polyfunctional intermediates.Condensation with 1-(methoxyoxalyl)imidazole gives the tetrafunctionalized methyl 4-(1,3-dioxolan-2-yl)-3-nitro-2-oxobutanoate (13), which, however, decomposed on attempted deprotection of the ester function.The syntheses in excellent yields of simple α-nitro ketones and α-nitro esters from acylimidazoles and nitroethane and 2-nitropropane are also described.