828933-87-5

Upstream product

• 51061-83-7 2,4-dihydroxy-5-methoxybenzaldehyde 
• 2916-68-9 2-(Trimethylsilyl)ethanol 

Downstream Products

• 720712-25-4 carbonic acid tert-butyl ester 2-formyl-4-methoxy-5-(2-trimethylsilanyl-ethoxy)-phenyl ester 
• 720712-36-7 (2S,4R)-6-Methoxy-4-phenyl-7-(2-trimethylsilanyl-ethoxy)-chroman-2-ol 
• 720712-34-5 {2-[(2S,4R)-6-Methoxy-4-phenyl-2-((1R,2S)-2-phenyl-cyclohexyloxy)-chroman-7-yloxy]-ethyl}-trimethyl-silane 
• 828933-82-0 {2-[2,5-Dimethoxy-4-((R)-1-phenyl-3-phenylselanyl-propyl)-phenoxy]-ethyl}-trimethyl-silane 
• 828933-81-9 2-((R)-3-Hydroxy-1-phenyl-propyl)-4-methoxy-5-(2-trimethylsilanyl-ethoxy)-phenol 
• 720712-37-8 (R)-3-[2,5-Dimethoxy-4-(2-trimethylsilanyl-ethoxy)-phenyl]-3-phenyl-propan-1-ol 
• 828933-83-1 {2-[2,5-Dimethoxy-4-((R)-1-phenyl-allyl)-phenoxy]-ethyl}-trimethyl-silane 
• 828933-80-8 (R)-6-Methoxy-4-phenyl-7-(2-trimethylsilanyl-ethoxy)-chroman-2-ol 

Relevant academic research and scientific papers

Diastereoselective [4+2] reactions of o-quinone methides with a chiral enol ether: Asymmetric synthesis of (+)-R-mimosifoliol

The first examples of enantioselective [4+2] cycloadditions of o-quinone methides (o-QMs) are reported. Their cycloaddition with trans-2-phenyl-1- cyclohexanol derived vinyl ether produces chiral benzopyrans. This procedure offers access to chiral aliphat

Enantioselective [4 + 2] cycloadditions of o-quinone methides: Total synthesis of (+)-mimosifoliol and formal synthesis of (+)-tolterodine

The first example of an enantioselective cycloaddition of an o-quinone methide (o-QM) with a chiral enol ether is described along with the total synthesis of (+)-mimosifoliol and the formal synthesis of (+)-tolterodine. These syntheses exemplify a three-c