82897-95-8

Basic information

• Product Name: 3-(Toluene-4-sulfinylmethyl)-benzo[d]isoxazole
• Synonyms: 3-(Toluene-4-sulfinylmethyl)-benzo[d]isoxazole
• CAS NO: 82897-95-8
• Molecular Weight: 271.34
• Mol File: 82897-95-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(Toluene-4-sulfinylmethyl)-benzo[d]isoxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(Toluene-4-sulfinylmethyl)-benzo[d]isoxazole(82897-95-8)
• EPA Substance Registry System: 3-(Toluene-4-sulfinylmethyl)-benzo[d]isoxazole(82897-95-8)

Safety Data

• Hazardous Substances Data: 82897-95-8(Hazardous Substances Data)

Upstream product

• 117343-45-0 (1,2-benzisoxazol-3-yl)(p-tolylthio)acetic acid 
• 10486-08-5 sodium p-thiocresolate 
• 37924-67-7 α-bromo-1,2-benzisoxazole-3-acetic acid 
• 82897-93-6 3-p-Tolylsulfanylmethyl-benzo[d]isoxazole 

Downstream Products

• 75326-25-9 C₁₅H₁₄N₂O₂S 
• 81981-85-3 C₁₅H₁₃ClN₂O₂S 
• 75326-30-6 C₁₅H₁₃BrN₂O₂S 
• 75326-38-4 C₁₅H₁₃BrN₂O₂S 
• 75326-35-1 C₁₅H₁₃ClN₂O₂S 

Relevant articles and documents

Halogenation Reaction of S-Aryl-Ssulfoximide

The reactions of the title free sulfoximide with N-bromosuccinimide (NBS) and N-chlorosuccinimide (NCS) afforded the corresponding α-halogenated "free" sulfoximides in good yields.The α-bromination proceeded via a facile N-bromination followed by a bromine transfer reaction of the resulting N-bromosulfoximide.The NCS chlorination, in contrast, proceeded via direct α-chlorination, not via N-chlorination.However, in the presence of potassium carbonate or silica gel N-chlorination occured predominantly in the NCS chlorination.Keywords---1,2-benzisoxazole; halogenation; N-halosulfoximide; α-halo sulfoximide; rearrangement; induction period