82946-70-1Relevant academic research and scientific papers
THE SYNTHESIS OF 1,2,3-TRISUBSTITUTED BENZENES. FURTHER COMMENTS ON BENZYNES DERIVED FROM ARYL OXAZOLINES
Meyers, A. I.,Pansegrau, Paul D.
, p. 4935 - 4938 (2007/10/02)
Further investigation of organolithium addition to the 2,3-benzyne of aryl oxazolines reveals that addition takes place to give the 3-lithio (kinetic) and/or 2-lithio (thermodynamic) products depending on the nature of the organolithium reagent.
BENZYNE DERIVED FROM ARYLOXAZOLINES. A VERSATILE INTERMEDIATE.
Meyers, A. I.,Rieker, William
, p. 2091 - 2094 (2007/10/02)
The benzyne derived from m-chlorophenyl oxazoline adds nucleophiles regiospecifically producing m-substituted products.Electrophiles are also trapped furnishing 1,2,3-trisubstituted benzenes.
