82959-22-6Relevant academic research and scientific papers
Pentafluoroethylating compositions
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Paragraph 0209, (2015/02/25)
The present invention relates to pentafluoroethylating compositions, processes for obtaining them, and their use in pentafluoroethylation reactions.
PENTAFLUOROETHYLATING COMPOSITIONS
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Page/Page column 42; 43, (2015/02/25)
The present invention relates to pentafluoroethylating compositions, processes for obtaining them, and their use in pentafluoroethylation reactions.
PERFLUOROALKYLATION OF ALKYNES WITH RfI(Ph)OSO2CF3
Umemoto, Teruo,Kuriu, Yuriko,Miyano, Osamu
, p. 3579 - 3582 (2007/10/02)
Perfluoralkylation of alkynes with RfI(Ph)OSO2CF3 is desdribed.This offers the first example of electrophilic perfluoroalkylation of alkynes.
A NEW METHOD FOR THE PREPARATION OF α-(PERFLUOROALKYL) CARBONYL AND γ-(PERFLUOROALKYL)-α,β-UNSATURATED CARBONYL COMPOUNDS
Umemoto, Teruo,Kuriu, Yuriko,Nakayama, Shin-ichi,Miyano, Osamu
, p. 1471 - 1474 (2007/10/02)
RfI(Ph)OSO2CF3 or RfI(Ph)OSO3H smoothly reacted with various trimethylsilyl enol ethers under mild conditions to give α(perfluoroalkyl) carbonyl and γ=)perfluoroalkyl)-α,β-unsaturated carbonyl compounds in high yields.
