84201-76-3Relevant academic research and scientific papers
Oxidative trifluoromethylation and fluoroolefination of unactivated olefins
Wu, Ye-Bin,Lu, Guo-Ping,Yuan, Tao,Xu, Zhu-Bing,Wan, Li,Cai, Chun
, p. 13668 - 13670 (2016/11/29)
Fluorine-containing organic compounds are gaining increasing importance in medicinal chemistry. Described herein is a mild and efficient method for the radical addition of olefins with TMSCF3 and TMSCF2R (R = COOEt or CF3) to deliver various α-trifluoromethylated ketones and α-fluoroolefinated ketones.
Regioselective synthesis of β-fluoro-α,β-unsaturated ketones by the reaction of β-diketones with DFMBA
Sano, Keisuke,Fukuhara, Tsuyoshi,Hara, Shoji
experimental part, p. 708 - 713 (2010/04/05)
The deoxyfluorination reaction of β-diketones with N,N-diethyl-α,α-difluoro-m-methylbenzylamine (DFMBA) gave β-fluoro-α,β-unsaturated ketones in good yields. The reaction proceeded regioselectively, and only one regioisomer was obtained from the unsymmetr
PERFLUOROALKYLATION OF ALKYNES WITH RfI(Ph)OSO2CF3
Umemoto, Teruo,Kuriu, Yuriko,Miyano, Osamu
, p. 3579 - 3582 (2007/10/02)
Perfluoralkylation of alkynes with RfI(Ph)OSO2CF3 is desdribed.This offers the first example of electrophilic perfluoroalkylation of alkynes.
