82992-46-9Relevant academic research and scientific papers
HIGHLY STEREOCONTROLLED REDUCTION OF α'-ALKOXYENONES TO GIVE EITHER THE THREO OR ERYTHRO ALLYLIC 1,2-DIOL. ASSIGNMENT OF THE THREO CONFIGURATION TO THE C-15,C-16 DIOL OF PUMILIOTOXIN B.
Overman, Larry E.,McCready, Russell J.
, p. 2355 - 2358 (2007/10/02)
Model studies indicate that the allylic diol of pumiliotoxin B has the threo configuration, and that this functionality can be prepared with excellent stereocontrol by reduction of an α'-t-butyldiphenylsilyloxyenone.
