82994-41-0

Basic information

• Product Name: β-tributylstannylpropionaldehyde
• Synonyms: β-tributylstannylpropionaldehyde
• CAS NO: 82994-41-0
• Molecular Weight: 347.128
• Mol File: 82994-41-0.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: β-tributylstannylpropionaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: β-tributylstannylpropionaldehyde(82994-41-0)
• EPA Substance Registry System: β-tributylstannylpropionaldehyde(82994-41-0)

Safety Data

• Hazardous Substances Data: 82994-41-0(Hazardous Substances Data)

Upstream product

• 688-73-3 tri-n-butyl-tin hydride 
• 76782-82-6 tert-Butyldimethyl(prop-2-ynyloxy)silane 
• 1983-10-4 tributyltin fluoride 
• 107-19-7 propargyl alcohol 
• 34241-39-9 azobisisobutyronitrile 
• 90838-72-5 (E)-tert-butyldimethyl[3-(tributylstannyl)prop-2-enyloxy]silane 
• 82101-74-4 methyl (E)-3-(tributylstannyl)acrylate 

Downstream Products

• 83413-35-8 (2E,5E)-6-phenylhexa-2,5-dien-1-ol 
• 1667-00-1 benzylcyclopropane 
• 515814-06-9 (E)-2-(4-benzyloxy-3-methoxyphenyl)-5-(3-hydroxypropenyl)-7-methoxybenzofuran 
• 868564-65-2 (-)-(S)-2-(E)-4-(Z)-5-phenyl-4-(p-tolylsulfinyl)penta-2,4-dien-1-ol 
• 211424-21-4 (2E,4Z)-4-((S)-Toluene-4-sulfinyl)-nona-2,4-dien-1-ol 
• 82994-46-5 1-(Cyclopropyl-phenyl-methylsulfanyl)-2,4-dinitro-benzene 
• 1394822-51-5 (Z)-2-methylenedec-3-en-1-ol 
• 77657-78-4 (2Z,4E)-undeca-2,4-dien-1-ol 
• 1369852-97-0 (E)-N-{2-[1-benzyl-2-(3-hydroxyprop-1-en-1-yl)-5-methoxy-1H-indol-3-yl]ethyl}-2,2,2-trifluoroacetamide 
• 1369852-94-7 (E)-N-{2-[1-benzyl-2-(3-hydroxyprop-1-enyl)-1H-indol-3-yl]ethyl}-2,2,2-trifluoroacetamide 
• 1333170-28-7 (6S)-6-({(2E)-3-[4-benzyloxyphenyl]-2-propenyl}oxy)-2-nitro-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine 
• 1321530-47-5 (S,2E,4E)-6-(((tert-Butyldiphenylsilyl)oxy)methyl)octa-2,4-dien-1-ol 
• 1268372-64-0 (E)-2,2,2-trifluoro-N-(2-(3-hydroxyprop-1-enyl)-4,5-dimethoxyphenethyl)acetamide 
• 1268372-68-4 (E)-N-(2-(3-hydroxyprop-1-enyl)-4,5-dimethoxyphenethyl)acetamide 

Relevant articles and documents

Synthesis of Optically Active N -(4-Hydroxynon-2-enyl)pyrrolidines: Key Building Blocks in the Total Synthesis of Streptomyces coelicolor Butanolide 5 (SCB-5) and Virginiae Butanolide A (VB-A)

Starting from 5-methylhexanal and (S)-configured N -propargylprolinol ethers, coupling delivered N -(4-hydroxynon-2-ynyl)prolinol derivatives as mixtures of C4 diastereomers. Resolution of the epimers succeeded after introduction of an (R)-mandelic ester derivative and subsequent HPLC separation. Alternatively, suitable oxidation gave the corresponding alkynyl ketone. Midland reagent controlled diastereoselective reduction afforded a defined configured propargyl alcohol with high selectivity. LiAlH 4reduction and Mosher analyses of the allyl alcohols enabled structure elucidation. The suitably protected products are used as key intermediates in enantioselective Streptomyces γ-butyrolactone signaling molecule total syntheses.

PROBE FOR DETECTING CARBAPENEM-RESISTANT BACTERIA AND USE THEREOF

The present disclosure relates to a compound represented by Chemical Formula 1, a probe for detecting antibiotic-resistant bacteria, which includes the compound, a composition containing the compound, a kit including the compound and a method for detectin

Total Synthesis of Lajollamycin B

The first total synthesis of lajollamycin B, a structurally novel nitro-tetraene spiro-β-lactone/γ-lactone antibiotic, is described. The convergent synthesis involves the construction of the C8′–C11′ nitrodienylstannane and its coupling with the segment prepared from the C1′–C7′ ω-iodoheptadienoic acid and the right-hand heterocyclic fragment, which has been utilized for our previous syntheses of oxazolomycin A. The revision of the geometry of the terminal Δ10′, 11′-double bond from E to Z is also described for the structure of natural lajollamycin B.