83001-47-2Relevant academic research and scientific papers
STEREOCONTROLLED FORMATION OF 1,2-DIHYDROINDOLES
Veenstra, S.J.,Fortgens, H.P.,Vijn, R.J.,Jong, B.S. de,Speckamp, W.N.
, p. 1147 - 1156 (2007/10/02)
Imines 4 cyclize stereoselectively to dihydroindoles 2 upon use of a Li or Na alkoxide-alcohol combination.Depending on the type of alcohol applied either cis (2C) or trans (2T) spiroindolines 2 are formed.In case of imines 4 derived from electron-rich ar
STEREO- AND ENANTIOSELECTIVE SYNTHESES OF 2,3-DIHYDROINDOLE DERIVATIVES
Spackamp, W. Nico
, p. 211 - 234 (2007/10/02)
2,3-Dihydroindoles (2,3-Indolines) can be obtained in a highly stereoselective fashion through 1,5-electrocyclization of ortho-substituted aminobenzenes.The scope and mechanism of this novel process are discussed and also some applications.In presence of
