83037-16-5Relevant academic research and scientific papers
PREPARATION OF MONOPHENYLTHALLIUM(III)DIBENZO-18-CROWN-6 COMPLEXES WITH A SOFT LIGAND:ClO4
Kawasaki, Yoshikane,Yokota, Wataru,Enomoto, Norihide
, p. 941 - 942 (1982)
Monophenylthallium(III) complexes with a Tl-I or Tl-SR bond were prepared in the presence of dibenzo-18-crown-6.These complexes are stable in the air and to heat to their melting points.In the hydrogen sulfide complex, ν(S-H) band was found at 2570 cm-1 and δ(Tl-SH) was observed at 1.15 ppm with 2J(Tl-SH)=405 Hz in CH2Cl2 solution.
